I think you're looking for one of these? Both have kagome and sesshomaru becoming lovers. I remember the scene you're describing but can't remember if either of these are right.
A Taste Of Perfection COMPLETED
RATED MA
Things go from complicated to downright ridiculous as Kagome finds herself the focus of one overly curious dog lord’s interest. Can she juggle all the responsibilities that come with being the shikon miko AND the attention of a daiyoukai?
A Blue Ribbon COMPLETED
RATED MA
It all began with a blue ribbon. She sparked his curiosity with her peculiar habits. He awakened her lust with his alluring nature. Can this develop into something more than mere physical attraction?